煤直接液化油中混合酚的分离研究

利用分子筛择形特点，对煤直接液化油中的混合酚实施高效分离。本研究选取间甲酚和对甲酚作为分离煤直接液化油馏分段混合酚的模型化合物，采用化学液相沉积法对HZSM-5吸附剂的孔口结构进行改变，分析分子筛硅铝比及颗粒粒径对模型化合物间甲酚和对甲酚吸附分离性能的影响，以获得高性能固相吸附剂，并将其应用于180-190℃馏分段混合酚分离。结果表明，当分子筛硅铝比为25、粒径为3-5 μm时，分子筛的孔口结构调节效果最优；当正硅酸乙酯的最小用量为0.2 mL/g时，固相吸附剂的吸附量为0.03 g/g，对甲酚选择性高于95%。由于外表面沉积物对吸附剂的孔口结构变化，导致对甲酚选择性的提高。进一步采用HZSM-5（1）吸附剂对真实煤直接液化油混合酚的分离中发现，苯酚和对甲酚的选择性均达到100%。     

Molecular design of ambipolar redox-active molecules II: closed-shell systems

This mini-review highlights key structural features that should be taken into account when creating ambipolar redox-active closed-shell metal-free molecules. This type of compound is strongly required for the fabrication of all-organic ‘poleless’ batteries and semiconductors. The suggested strategies aimed at stabilization of both oxidized (cationic) and reduced (anionic) redox-states are based on the comprehensive analysis of the most successful structures taken from the recent publications.     

Sobolev Stability of Plane Wave Solutions to the Nonlinear Schrödinger Equation

This article explores the questions of long time orbital stability in high order Sobolev norms of plane wave solutions to the NLSE in the defocusing case.     

Hydrogenation of acetylene into ethane–ethene mixtures over modified Pd–alumina catalysts

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一带一路背景下企业地域影响力发展的规划研究

面对一个分布在新地理区域的新市场,合理规划区域服务影响力的发展战略对企业至关重要。本文假设企业的服务影响力在地理区域上的发展可以用其地理上分布的立足点来表示。单个立足点覆盖有限范围内的地理区域,并且在一个特定时刻用所有立足点所覆盖地理区域的总和来表示企业该时刻的发展状态。由于资源限制,企业对经济发展迅速的区域的覆盖必须在一定时间内逐步完成。因此,在发展时期内如何确定立足点的位置并使其位于知名城市中,是企业管理者亟待解决的问题。针对这个问题,本文首先基于时间序列预测方法建立了区域经济指标评估模型;然后使用集合覆盖理论提出了以成本和满意度为目标的选址优化模型并使用分支定界算法求解该模型;最后,使用从“一带一路”地区收集的数据对模型进行了检验。结果表明,该方法对有相关问题的企业具有较大的参考价值。     

Stability of Multiplier Ideal Sheaves

Chinese Annals of Mathematics, Series B - In the present article, the authors find and establish stability of multiplier ideal sheaves, which is more general than strong openness.     

A study of properties of adaptive quadratic grids for three-dimensional near-surface field computations

Curved geometries and the corresponding near-surface fields typically require a large number of linear computational elements. High-order numerical solvers have been primarily used with low-order meshes. There is a need for curved, high-order computational elements. Typical near-surface meshes consist of hexahedral and/or prismatic elements. The present work studies the employment of quadratic meshes that are relatively coarse for field simulations. Directionally quadratic high-order elements are proposed for the near-surface field regions. The quadratic meshes are compared with the conventional low-order ones in terms of accuracy and efficiency. The cases considered include closed surface volume calculations, as well as computation of gradients of several analytic fields. A special method of adaptive local quadratic meshes is proposed and evaluated. Truncation error analysis for quadratic grids yields comparison with the conventional linear hexahedral/prismatic meshes, which are subject to typical distortions such as stretching, skewness, and torsion.     

HyperFLOW软件非结构网格亚跨声速湍流模拟的验证与确认

计算流体力学(computational fluid dynamics,CFD)数值模拟在航空航天等领域发挥越来越重要的作用,然而CFD数值模拟结果的可信度仍然需要通过不断地验证与确认来提高.本文给出了从制造解精度测试、简单到复杂外形湍流模拟网格收敛性研究等三个方面开展CFD软件验证与确认的方法,并对自主研发的CFD软件平台HyperFLOW在非结构网格上模拟亚跨声速湍流问题的能力进行了验证与确认.首先通过基于Euler方程和标量扩散方程的制造解精度测试,分别验证了HyperFLOW在非结构网格上对Euler方程和黏性项的求解精度,结果表明其能够在任意非结构网格上达到设计的二阶精度. 其次,通过NASATurbulence Modeling Resource中的湍流平板、二维翼型近尾迹流动、二维Bump等几个典型的亚声速湍流算例的网格收敛性研究,量化考察了数值结果的观测精度阶和网格收敛性指数,并与国外知名CFD解算器CFL3D,FUN3D的计算结果进行了对比,验证了HyperFLOW对简单湍流问题的模拟能力,且具有良好的网格收敛性和计算精度(阶). 最后,通过NASA CommonResearchModel标模定升力系数的网格收敛性研究和升阻极曲线预测,验证了软件在复杂外形亚跨声速湍流流动数值模拟中也具有良好的可信度.